Phase change material selection for thermal processes working under partial load operating conditions in the temperature range between 120 and 200 ºC

摘要

In some processes, latent heat thermal energy storage (TES) systems might work under partial load operating conditions (the available thermal energy source is discontinuous or insufficient to completely charge the phase change material (PCM)). Therefore, there is a need to study how these conditions affect the discharge process to design a control strategy that can benefit the user of these systems. The aim of this paper is to show and perform at laboratory scale the selection of a PCM, with a phase change temperature between 120 and 200 ºC, which will be further used in an experimental facility. Beyond the typical PCM properties, sixteen PCMs are studied here from the cycling and thermal stability point of view, as well as from the health hazard point of view. After 100 melting and freezing cycles, seven candidates out of the sixteen present a suitable cycling stability behaviour and five of them show a maximum thermal-stable temperature higher than 200 ºC. Two final candidates for the partial loads approach are found in this temperature range, named high density polyethylene (HDPE) and adipic acid.